Halide precursors

Rhenium Hexaftoride ReF6

  • CAS Registry Number: 10049-17-9

  • Molar mass: 300.197 g/mol

  • Boiling point: 33.8°C

  • Triple point: 18.7°C, 436.5 Torr

Saturated vapor pressure.

# T -- temperature, C
# P -- saturated vapor pressure, Torr
#  J. Chem. Soc., 1961, 1563-1568
if 19.0 <= T <= 33.8:
    P = 10 ** (7.732 - 1489.1/(T + 273.15))
if -1.9 <= T <= 18.0:
    P = 10 ** (8.539 - 1724.7/(T + 273.15))
if -50 <= T <= -1.9:
    P = 10 ** (10.11 - 2151.2/(T + 273.15))

ReF<sub>6</sub> saturated vapor pressure

Organic precursors

Rhenium carbonyl Ni2(CO)10

Saturated vapor pressure.

# T -- temperature, C
# P -- saturated vapor pressure, Torr
# V.G. Syrkin. Chemistry and Technology of Carbonyl Metals
P = 10 ** (10.68 - 4152 / (T + 273.15))

Bibliography

  1. V.G. Syrkin. Chemistry and Technology of Carbonyl Metals. Moscow, Chemistry 1972. [in Russian]

  2. George H. Cady and George B. Hargreaces, The Vapour Pressures of Some Heavy Transition-metal Hexafluorides. J. Chem. Soc., 1961, 1563-1568 doi:10.1039/JR9610001563